An interesting question...what is the relationship between psychology and falling in love?
It seems that "falling in love" has so many meanings that it would require a family of psychological descriptions.
...i will clarify...is there a psychology of love and attraction?
There are CAT & PET scans, blood tests for hormones (and etc!) readily available just about everywhere for decades now, ever since the technology developed. Got forth & find them!
The relationship can be explained as "Falling in love" is the act where psychology is study of the act.
Psychology defined as the scientific study of the human mind and its functions, especially those affecting behavior in a given context.
Falling in love is the development of strong feelings of attachment and love, usually towards another person. The term is metaphorical, emphasising that the process, like the physical act of falling, is sudden, uncontrollable and leaves the lover in a vulnerable state, similar to "fall ill" or "fall into a trap". Wikipedia